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Details
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Phase equilibria in the system ZrO2-InO1.5
Author |
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Sasaki, Kazunari; Bohac, Petr; Gauckler, Ludwig J. |
Year |
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1993 |
Type
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Journal Article |
Journal |
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J. Am. Ceram. Soc. |
Volume |
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76 |
Issue |
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3 |
Pages |
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689-698 |
Date |
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1993/3 |
Custom 1 |
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JA |
Custom 2 |
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SOFC |
Abstract |
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Phase equilibria in the system ZrO2-InO1.5 have been investigated in the temperature range from 800[deg] to 1700[deg]C. Up to 4 mol%, InO1.5 is soluble in t-ZrO2 at 1500[deg]C. The martensitic transformation temperature m [lsbr;]Arrow Right[rsbr;] t of ZrO2 containing InO1.5 is compared with that of ZrO2 solid solutions with various other trivalent ions with different ionic radii. The diffusionless c [lsbr;]Arrow Right[rsbr;] t prime phase transformation is discussed. Extended solid solubility from 12.4 +/- 0.8 to 56.5 +/- 3 mol% InO1.5 is found at 1700[deg]C in the cubic ZrO2 phase. The eutectoid composition and temperature for the decomposition of c-ZrO2 solid solution into t-ZrO2 + InO1.5 solid solutions were determined. A maximum of about 1 mol% ZrO2 is soluble in bcc InO1.5 phase. Metastable supersaturation of ZrO2 in bcc InO1.5 and conditions for phase separation are discussed. [Author abstract; 35 Refs; In English] |
URL |
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Record Number |
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126 |
Group
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nonmet |
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