printlogo
http://www.ethz.ch/index_EN
Nonmetallic Inorganic Materials
 
print
  

Details

Back to List

Phase compatibilities in the Bi-poor region of the system Bi-Sr-Ca-O at 820° and 900°C in air

Author   Müller, R.; Cantoni, M.; Gauckler, L. J.
Year   1995
Type   Journal Article
Journal   Physica C
Volume   243
Issue   1-2
Pages   103-112
Date   1995/2/20
Custom 1   JA
Custom 2   SUPRA
Abstract   The phase equilibria in the system Bi---Sr---Ca---O have been clarified in the Bi-poor region around the solid solutions Bi2Sr1-xCa1+xOy, Bi2Sr3-xCaxOy, Bi9Sr11-xCa5+xOy, BiSr3-xCaxOy, and (Ca, Sr)O on two isothermal sections at 900 and 820[deg]C in air. The lattice constants along the solid solution ranges were determined by X-ray diffraction. The phase Bi2Sr3-xCaxOy is stable over a wide range of Sr : Ca ratios above ~ 880[deg]C in air. The crystal structure of the ternary phase Bi9Sr 11-xCa5+xOy is monoclinic (Pc) with a=11.195(2) a, b=5.914(1) a, c=19.972(4) a, [beta]=101.78(1)[deg] for the composition Bi : Sr : Ca=36.0 : 28.7 : 35.3. Both solid solutions show a remarkable temperature dependence.
Notes   TY - JOUR
URL  
Record Number   202
Group   nonmet

Back to List

 

Wichtiger Hinweis:
Diese Website wird in älteren Versionen von Netscape ohne graphische Elemente dargestellt. Die Funktionalität der Website ist aber trotzdem gewährleistet. Wenn Sie diese Website regelmässig benutzen, empfehlen wir Ihnen, auf Ihrem Computer einen aktuellen Browser zu installieren. Weitere Informationen finden Sie auf
folgender Seite.

Important Note:
The content in this site is accessible to any browser or Internet device, however, some graphics will display correctly only in the newer versions of Netscape. To get the most out of our site we suggest you upgrade to a newer browser.
More information

© 2019 ETH Zurich | Imprint | Disclaimer | 14 March 2006
top