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Designing macroporous polymers from particle-stabilized foams

Author   Wong, J. C. H.; Tervoort, E.; Busato, S.; Gonzenbach, U. T.; Studart, A. R.; Ermanni, P.; Gauckler, L. J.
Year   2010
Type   Journal Article
Journal   Journal of Materials Chemistry
Volume   20
Issue   27
Pages   5628-5640
ISSN   0959-9428
Accession Numer   WOS:000279322600008
Abstract   Particle-stabilized liquid foams provide a general route for producing low-density macroporous materials from melt-processable and intractable thermoplastic polymers. In this paper, we demonstrate how these liquid foams can be used to design macroporous polymers with tailored microstructures and properties by adjusting the various processing parameters. By varying the size, concentration, and wettability of the particles in the colloidal suspensions and controlling the frothing, drying, and sintering conditions, macroporous materials with porosities between 33 and 95% and median pore sizes (D-50) between 13 and 634 mu m were obtained. This foaming process is applicable to a wide range of hydrophobic materials and is demonstrated here on commercially available polymeric powders of poly(tetrafluoroethylene) (PTFE), poly(vinylidene fluoride) (PVDF), poly(ether imide) (PEI), and poly(ether ether ketone) (PEEK).
Notes   Times Cited: 1
URL   Access publication [Website]
Record Number   740
Group   nonmet

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